Tetrabutylphosphonium ions as a new swelling/delamination agent for layered compounds.
نویسندگان
چکیده
The swelling and exfoliation behavior of protonated layered oxides using an organo-phosphonium base, tetrabutylphosphonium hydroxide (TBPOH), was examined for the first time. The action of the aqueous solution induced massive interlayer expansion up to ~100-fold. The swollen crystals were immediately broken and completely exfoliated into unilamellar nanosheets in 1-2 h by shaking.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 69 شماره
صفحات -
تاریخ انتشار 2014